Material Safety Data Sheet Revision Number: 1 Issue date: 7/26/2009
1. PRODUCT AND COMPANY IDENTIFICATION Product name: Magnesium Touch-Up Kit Product type: Conversion coating
Company address: DGR Industrial Products, Inc. 4435 North First Street, Suite #184 Livermore, California 94551 Phone: (408) 221-7122 For Chemical Emergency: Call CHEMTREC at 800.424.9300 Internet: www.chemical-supermarket.com
2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
HMIS: Physical state: Liquid HEALTH: 3 Color: Orange FLAMMABILITY: 0 Odor: None PHYSICAL HAZARD: 0 Personal Protection: See MSDS Section 8
DANGER—CORROSIVE!: CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION. MAY CAUSE EYE AND SKIN BURNS. MAY CAUSE ALLERGIC SKIN REACTION. POSSIBLE CANCER HAZARD.
Relevant routes of exposure: Skin, Inhalation, Eyes
Potential Health Effects Inhalation: Mists, vapors or liquid may cause severe irritation or burns. Prolonged or repeated breathing may cause ulceration of nasal membranes.
Skin contact: Contact with broken skin may lead to formation of firmly marginated "chrome sores". Product contains chromium, which may cause an allergic skin sensitization reaction. Massive overexposures may lead to kidney failure and death. A component in this product may be harmful or fatal if absorbed through the skin, especially if skin is damaged.
Eye contact: This product is severely irritating to the eyes and may cause irreversible damage including burns and blindness. Contact with this product may cause severe eye damage.
Ingestion: This product may produce corrosive damage to the gastrointestinal tract if it is swallowed.
Existing conditions aggravated by exposure: Eye, skin and respiratory disorders. Kidney disorders. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). See Section 11 for additional toxicological information.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous components CAS NUMBER %
Chromic acid 7738-94-5 1 – 5
4. FIRST AID MEASURES
Inhalation: If mist or vapor of this product is inhaled, remove person immediately to fresh air. Seek medical attention if symptoms develop or persist.
Skin contact: Remove contaminated clothing and footwear. For skin contact, flush with large amounts of water. Seek immediate medical attention. If irritation persists, repeat flushing and get medical attention. Discard any shoes or clothing items that cannot be decontaminated.
Eye contact: In case of contact with the eyes, rinse immediately with plenty of water for 15 minutes, and seek immediate medical attention.
Ingestion: Get immediate medical attention. Do not induce vomiting. Give one to two glasses of water or milk. Never give anything by mouth to a victim who is unconscious or is having convulsions.
Notes to physician: Treat symptomatically and supportively.
5. FIRE FIGHTING MEASURES Flash point: 121.1 °C (249.98 °F) calculated Autoignition temperature: Not applicable Flammable/Explosive limits - lower: Not applicable Flammable/Explosive limits - upper: Not applicable Extinguishing media: Use media appropriate for surrounding material.
Special firefighting procedures: Wear full protective clothing. Wear self-contained breathing apparatus. Unusual fire or explosion hazards: This product is an aqueous mixture which will not burn. Hazardous combustion products: Irritating and toxic gases or fumes may be released during a fire.
6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel.
Environmental precautions: Prevent further leakage or spillage if safe to do so. Wear appropriate protective equipment and clothing during clean-up. Block any potential routes to water systems.
Clean-up methods: Absorb spill with inert material. Shovel material into appropriate container for disposal.
7. HANDLING AND STORAGE Handling: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Provide adequate ventilation. For industrial use only. Do not take internally.
Storage: For safe storage, store between 4.4 °C (39.9 °F) and 37.8 °C (100°F) Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials. Protect from freezing. For information on product shelf life, please review labels on container or check the Technical Process Instruction. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed.
Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER
Chromic acid 0.05 mg/m3 TWA None None (as Cr) 0.1 mg/m3 Ceiling 0.005 mg/m3 TWA (SKIN)0.0025 mg/m3 OSHA ACT 29 CFR 1910.1026
Engineering controls: Provide local and general exhaust ventilation to effectively remove and prevent buildup of any vapors or mists generated from the handling of this product.
Respiratory protection: If ventilation is not sufficient to effectively prevent buildup of aerosols, mists or vapors, appropriate NIOSH/MSHA respiratory protection must be provided.
Eye/face protection: Wear chemical goggles; face shield (if splashing is possible).
Skin protection: Chemical resistant, impermeable gloves. Gloves should be tested to determine suitability for prolonged contact. Use of impervious apron and boots are recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Orange Odor: None Odor threshold: Not available pH: 1.2 - 1.4 Vapor pressure: Not determined Boiling point/range: 200 °F (93.3 °C) Melting point/ range: Not available Specific gravity: 1.00 - 1.03 at 15.6 °C (60.08 °F) Vapor density: Not determined Flash point: 121.1 °C (249.98 °F) calculated Flammable/Explosive limits - lower: Not applicable Flammable/Explosive limits - upper: Not applicable Autoignition temperature: Not applicable Evaporation rate: Not available Solubility in water: Complete Partition coefficient (n-octanol/water): Not determined VOC content: Not applicable
10. STABILITY AND REACTIVITY Stability: Stable at normal conditions. Hazardous reactions: Will not occur. Hazardous decomposition products: Irritating and/or toxic fumes and gases may be emitted upon the product's decomposition. Incompatible materials: Avoid contact with organic materials, oils, greases, and any oxidizable materials. Conditions to avoid: None identified.
11. TOXICOLOGICAL INFORMATION
Hazardous components: Chromic Acid NTP Carcinogen: Known carcinogen IARC Carcinogen: Group 1 OSHA Carcinogen: Yes
Hazardous components Health Effects/Target Organs
Chromic acid Allergen, Blood, Human carcinogen, Central nervous system, Corrosive, Developmental, Eyes, Gastrointestinal tract, Irritant, Kidney, Liver, Mutagen, Reproductive, Respiratory
12. ECOLOGICAL INFORMATION Ecological information: Not available
13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.
Hazardous waste number: This product, if discarded directly, would be a characteristic RCRA corrosive waste (D002). This product contains chromium which is a hazardous waste (D007).
14. TRANSPORT INFORMATION
U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Chromic acid solution Hazard class or division: 8 Identification number: UN 1755 Packing group: III
International Air Transportation (ICAO/IATA) Proper shipping name: Chromic acid solution Hazard class or division: 8 Identification number: UN 1755 Packing group: III
Water Transportation (IMO/IMDG) Proper shipping name: CHROMIC ACID SOLUTION Hazard class or division: 8 Identification number: UN 1755 Packing group: III
15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12(b) Export Notification: Chromic acid (CAS# 7738-94-5). CERCLA/SARA Section 302 EHS: None above reporting de minimus CERCLA/SARA Section 311/312: Immediate Health, Delayed Health CERCLA/SARA 313: This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Chromic acid (CAS# 7738-94-5). CERCLA Reportable quantity: Chromic acid (CAS# 7738-94-5) 10 lbs. (4.54 kg) California Proposition 65: This product contains a chemical known in the State of California to cause cancer.
Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List.
WHMIS hazard class: D.2.A, D.2.B, E
16. OTHER INFORMATION
DISCLAIMER: The data contained in this document is furnished for information only and is believed to be reliable. However, DGR Industrial Products, Inc. does not assume responsibility for any results obtained by persons over whose methods DGR Industrial Products, Inc. has no control. It is the user's responsibility to determine the suitability of DGR’s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of DGR’s products. In light of the foregoing, DGR Industrial Products, Inc. specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of DGR’s products. DGR Industrial Products, Inc. further disclaims any liability for consequential or incidental damages of any kind, including lost profits.
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